Out of curiosity...
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...are there any tarot cards that signify someone who seems nice but isn't?
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Yes....many. The Knight of Cups can represent someone who isn't as they appear to be, the Magician can be the "trickster" or someone who is tricking or deceiving you in some way, the Moon can represent someone who is lying or deceiving you, any of the court cards really as all personalities have their Shadow sides.
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Interesting, thanks, Watergirl.